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Beilstein J. Org. Chem. 2013, 9, 2404–2409, doi:10.3762/bjoc.9.277
Graphical Abstract
Figure 1: Copper-catalyzed trifluoromethylation of various aryl iodides. Yields were determined by 19F NMR an...
Scheme 1: Observation of CuCF3 species in 19F NMR spectrum. aEquivalents based on Zn(CF3)I. bYields based on ...
Scheme 2: Proposed mechanism of copper-catalyzed trifluoromethylation.